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HLM-106

This specification describes the 106-type lithium-ion battery cathode material produced by Hunan Haili Lithium Technology Co., Ltd. (hereinafter referred to as Haili Lithium), with the molecular formula LiMn2O4.

classification:

Lithium battery

keyword:

haili

annex:


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DESCRIPTION

  1 Introduction

  This specification describes the 106-type lithium-ion battery cathode material produced by Hunan Haili Lithium Technology Co., Ltd. (hereinafter referred to as Haili Lithium), with the molecular formula LiMn2O4.

  2. Model: HLM-106

  3. Scope of application of the product

  It is suitable for high energy density low-speed electric vehicles, electric bicycles, electric tools, small energy storage and other fields. It is especially suitable for mixed use with ternary materials to produce mid-to-high-end lithium battery products with high cost performance, high capacity and high stability.

  4. Product Features

  This product is modified by element doping and special sintering process, which improves the comprehensive performance of ordinary lithium manganate. This material has good processing performance, high compaction density, high specific capacity, good cycle performance and good consistency.

  (1) The product particles are in complete regular spinel phase.

  (2) The comprehensive performance of the product is excellent. The 1C gram capacity at room temperature is greater than 118mAh/g, the cycle is 300 cycles, and the capacity retention rate is greater than 80%.

  (3) The compaction performance of the product is outstanding. The compacted density of the product is above 3.0 g/cm3.

  (4) There is no impurity phase in X-ray diffraction of the product.

  5. Physical indicators:

  5.1. Physical and chemical indicators

product name

Lithium manganese oxide

model

HLM-106

Chemical Composition and Physical Indicators

Analysis Project

standard value

typical value

testing method

Mn,%

≥57.0

58.85

volumetric method

Li,%

4.2±0.2

4.09

AAS

K,%

≤0.05

0.002

AAS

That,%

≤0.35

0.2510

AAS

Fe,%

≤0.01

0.0035

AAS

That,%

≤0.05

0.0157

AAS

With,%

≤0.01

0.0008

AAS

SO42-,%

≤1.5

1.18

gravimetric method

H 2 O, %

≤0.08

0.03

Karl Fischer method

Specific surface, m 2 /g

≤1.0

0.44

Specific surface tester

Magnetic substance, ppb

≤3500

2645

ICP

Tap density, g/ cm3

≥1.8

2.16

Tap Density Meter

Granularity (um)

(can be adjusted according to customer requirements)

D 10

≥3.0

3.90

Malvern particle size analyzer

D50

13~18

15.5

D 90

≤40

34.0

 

 5.2. Basic electrical performance indicators

project

standard value

typical value

testing method

Compacted density (g/cm 3 )

≥2.95

3.0

Reference data provided by downstream customers

Button power 1C discharge specific capacity (mAh/g)

≥118

121

Blue Electric Battery Tester

300-cycle cycle capacity retention at room temperature (1C charge and discharge)

≥80

82

Blue Electric Battery Tester

(Remarks: The relevant electrical performance data in this table are provided by the battery manufacturer for reference only, and the quality of the product is subject to the quality inspection sheet.)

 

5.3. Particle size distribution

 

5.4 Electron microscope image

 

 

  6. Packaging and storage conditions

  6.1. Packing method: Inner aluminum foil bag, vacuum packaging, outer carton, 25kg/box.

  6.2. Requirements for stacking layers: carton packaging ≤ 3 layers.

  6.3. Label style: the default Haili lithium battery shipping label, if the customer has special requirements, it can be implemented according to the label style provided by the customer.

  6.4. Storage conditions: Keep sealed and avoid direct sunlight. The recommended storage temperature is ≤37°C and the humidity is ≤50%RH. The shelf life is 1 year. If the product exceeds the shelf life, it should be inspected by our company and re-evaluated whether it can be used normally.

  6.5. Under the condition of unsealing, strictly control the storage humidity to ≤30%RH, and use it as soon as possible.

  7. Precautions for transportation

  When loading, do not place heavy objects on top of the cartons to prevent deformation of the cartons; prevent extrusion and sun and rain; use vehicles, trains, ships, planes and other vehicles for transportation.

  8. Suggestions for processing and use

  Positive electrode ratio: lithium manganate 95.0%~96.5%, SP 0.2%~0.5%, CNT 0.8%~1.5%, PVDF 2.5%~3.0%. It is recommended to use PVDF with a molecular weight greater than 1 million as the binder. If the binder is made by the suspension method, the dosage can be adjusted to 1.5% to 2.0%.

  Suggested negative electrode excess ratio: 8﹪~12﹪.

  It is recommended to use compaction: 2.90~3.05g/cm3.

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